Adding Tungsten to Synthesize Multi-metal Catalysts and Growing High-quality Carbon Nanotube
DOI:
https://doi.org/10.54691/ra2jhp18Keywords:
New Energy Materials, SWCNTs, Catalysts, CVD.Abstract
Recently, the need for sustainable development of a large population and the uneven distribution of resources have compelled people to make new breakthroughs in the energy revolution. The field of energy technology has been rapidly advancing, and researchers are increasingly focusing on energy materials. Single-walled carbon nanotubes (SWCNTs) play a vital role in this area. However, the initial challenge of producing SWCNTs in large batches hampers their widespread application. This study successfully synthesized a catalyst consisting of Fe-Co-W using an impregnation-calcination technique and achieved high-yield production of SWCNTs. The results indicate that the addition of W enables the formation of stable FeWO4 and CoWO4 phases from Fe and Co, significantly enhancing the system's stability. Subsequent growth of SWCNTs demonstrates that the catalyst performs exceptionally well, achieving a yield of 241% at a temperature of 900°C. This research contributes to the industrial-scale production of single-walled carbon nanotubes and the advancement of new energy materials.
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[1] Aguey‐Zinsou, F., Guo, Z., Ng, Y. H., & Wang, D. W. (2018). Future Energy Technology: Enabling New Science for a Sustainable Future. ChemPlusChem, 83(10), 890-892.
[2] Raj, T., Chandrasekhar, K., Kumar, A. N., Sharma, P., Pandey, A., Jang, M., ... & Kim, S. H. (2022). Recycling of cathode material from spent lithium-ion batteries: Challenges and future perspectives. Journal of Hazardous Materials, 429, 128312.
[3] Cui, Q., Wu, H., Qu, G., Li, J., & Wu, F. (2025). Contributing to the Sustainable Development of New Energy Materials: Current Research Status and Future Fate of Conductive Agents for Lithium Iron Phosphate Batteries. ChemistrySelect, 10(1), e202402896.
[4] Xu, J., Cai, X., Cai, S., Shao, Y., Hu, C., Lu, S., & Ding, S. (2023). High‐energy lithium‐ion batteries: recent progress and a promising future in applications. Energy & Environmental Materials, 6(5), e12450.
[5] Larcher, D., & Tarascon, J. M. (2015). Towards greener and more sustainable batteries for electrical energy storage. Nature chemistry, 7(1), 19-29.
[6] Sultana, I., Chen, Y., Huang, S., & Rahman, M. M. (2022). Recycled value-added circular energy materials for new battery application: Recycling strategies, challenges, and sustainability-a comprehensive review. Journal of Environmental Chemical Engineering, 10(6), 108728.
[7] Rashid, K., Omeema, U., Raza, A. H., Manzoor, A., Abbas, M. S., Mustafa, G., ... & Akram, M. (2025). Role of metal-organic frameworks (MOFs) in electrochemical energy storage devices including batteries and supercapacitors. Reviews in Inorganic Chemistry, (0).
[8] Landi, B. J., Ganter, M. J., Cress, C. D., DiLeo, R. A., & Raffaelle, R. P. (2009). Carbon nanotubes for lithium ion batteries. Energy & Environmental Science, 2(6), 638-654.
[9] Chabot, V., Higgins, D., Yu, A., Xiao, X., Chen, Z., & Zhang, J. (2014). A review of graphene and graphene oxide sponge: material synthesis and applications to energy and the environment. Energy & Environmental Science, 7(5), 1564-1596.
[10] Wang, Z., Xia, J., Ji, X., Liu, Y., Zhang, J., He, X., ... & Wang, C. (2024). Lithium anode interlayer design for all-solid-state lithium-metal batteries. Nature Energy, 9(3), 251-262.
[11] Tao, Z., Zhao, Y., Wang, Y., & Zhang, G. (2024). Recent advances in carbon nanotube technology: bridging the gap from fundamental science to wide applications. C, 10(3), 69.
[12] Zhou, S., Shi, X. L., Li, L., Liu, Q., Hu, B., Chen, W., ... & Chen, Z. G. (2025). Advances and Outlooks for Carbon Nanotube‐Based Thermoelectric Materials and Devices. Advanced Materials, 37(13), 2500947.
[13] Ijaz, H., Mahmood, A., Abdel-Daim, M. M., Sarfraz, R. M., Zaman, M., Zafar, N., ... & Benguerba, Y. (2023). Review on carbon nanotubes (CNTs) and their chemical and physical characteristics, with particular emphasis on potential applications in biomedicine. Inorganic Chemistry Communications, 155, 111020.
[14] Iijima, S. (1991). Helical microtubules of graphitic carbon. nature, 354(6348), 56-58.
[15] Li, W. Z., Xie, S. S., Qian, L. X., Chang, B. H., Zou, B. S., Zhou, W. Y., ... & Wang, G. (1996). Large-scale synthesis of aligned carbon nanotubes. Science, 274(5293), 1701-1703.
[16] 1Journet, C., Maser, W. K., Bernier, P., Loiseau, A., de La Chapelle, M. L., Lefrant, D. S., ... & Fischer, J. E. (1997). Large-scale production of single-walled carbon nanotubes by the electric-arc technique. nature, 388(6644), 756-758.
[17] Ebbesen, T. W., & Ajayan, P. M. (1992). Large-scale synthesis of carbon nanotubes. Nature, 358(6383), 220-222.
[18] Manawi, Y. M., Ihsanullah, Samara, A., Al-Ansari, T., & Atieh, M. A. (2018). A review of carbon nanomaterials’ synthesis via the chemical vapor deposition (CVD) method. Materials, 11(5), 822.
[19] Dong, Z., Li, B., Cui, C., Qian, W., Jin, Y., & Wei, F. (2020). Catalytic methane technology for carbon nanotubes and graphene. Reaction Chemistry & Engineering, 5(6), 991-1004.
[20] Chen, X., Pang, X., & Fauteux-Lefebvre, C. (2023). The base versus tip growth mode of carbon nanotubes by catalytic hydrocarbon cracking: Review, challenges and opportunities. Carbon Trends, 12, 100273.
[21] Castan, A., Forel, S., Fossard, F., Defillet, J., Ghedjatti, A., Levshov, D., ... & Loiseau, A. (2021). Assessing the reliability of the Raman peak counting method for the characterization of SWCNT diameter distributions: a cross characterization with TEM. Carbon, 171, 968-979.
[22] Dresselhaus, M. S., Dresselhaus, G., Saito, R., & Jorio, A. (2005). Raman spectroscopy of carbon nanotubes. Physics reports, 409(2), 47-99.
[23] Zhang Qiang, Zhao Mengqiang, Huang Jiaqi, Qian Weizhong,&Wei Fei (2008). Selective synthesis of single/double/multi walled carbon nanotubes using MgO supported Fe based catalysts Journal of Catalysis (English), 29 (11), 1138-1144
[24] Seidel, R., Duesberg, G. S., Unger, E., Graham, A. P., Liebau, M., & Kreupl, F. (2004). Chemical vapor deposition growth of single-walled carbon nanotubes at 600°C and a simple growth model. The Journal of Physical Chemistry B, 108(6), 1888-1893.
[25] Sanchez-Valencia, J. R., Dienel, T., Gröning, O., Shorubalko, I., Mueller, A., Jansen, M., ... & Fasel, R. (2014). Controlled synthesis of single-chirality carbon nanotubes. Nature, 512(7512), 61-64.
[26] Rao, R., Pint, C. L., Islam, A. E., Weatherup, R. S., Hofmann, S., Meshot, E. R., ... & Hart, A. J. (2018). Carbon nanotubes and related nanomaterials: critical advances and challenges for synthesis toward mainstream commercial applications. ACS nano, 12(12), 11756-11784.
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