Research Progress in Mechanical Properties of Polyvinyl Alcohol-Based Hydrogel Composites
DOI:
https://doi.org/10.54691/s7d36f08Keywords:
Polyvinyl alcohol, hydrogel, composite, mechanical property, strengthening and toughening.Abstract
Polyvinyl alcohol (PVA) hydrogels have broad application prospects in biomedical engineering, flexible electronics and other fields due to their excellent biocompatibility and chemical stability. However, traditional PVA hydrogels generally suffer from poor mechanical strength, low toughness and unsatisfactory fatigue resistance, which seriously restrict their practical applications. This paper systematically reviews the research progress in mechanical properties of PVA based hydrogel composites, focusing on the reinforcement mechanisms of strategies such as double network structure, nanoparticle composite, cross linking mode regulation, natural polymer composite and topological structure design. It summarizes the effects of cross linking density, polymer concentration and environmental factors on mechanical properties, deeply discusses the energy dissipation mechanisms and constitutive relationships, and prospects the future development directions in this field.Keywords.
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References
[1] Ahmed E M. Hydrogel: Preparation, characterization, and applications: A review[J]. Journal of Advanced Research, 2015, 6(2): 105-121.
[2] Jiang S, Liu S, Feng W. PVA hydrogel properties for biomedical application[J]. Journal of the Mechanical Behavior of Biomedical Materials, 2011, 4(7): 1228-1233.
[3] Gong J P. Why are double network hydrogels so tough?[J]. Soft Matter, 2010, 6(12): 2583-2590.
[4] Zhao X H, Chen X Y, Yuk H, et al. Soft materials by design: Unconventional polymer networks give extreme properties[J]. Chemical Reviews, 2021, 121(8): 4309-4372.
[5] ZOU Shaoshuang, YANG Peng, LIU Tao. Research Progress of High Mechanical Properties Hydrogels[J]. Journal of Liaocheng University(Natural Science Edition), 2023, 36(6): 1-11.
[6] Creton C. 50th Anniversary perspective: Networks and gels: Soft but dynamic and tough[J]. Macromolecules, 2017, 50(21): 8297-8316.
[7] Hassan C M, Peppas N A. Structure and morphology of freeze/thawed PVA hydrogels[J]. Macromolecules, 2000, 33(7): 2472-2479.
[8] Hassan C M, Peppas N A. Structure and applications of poly(vinyl alcohol) hydrogels produced by conventional crosslinking or by freezing/thawing methods[M]//Biopolymers·PVA Hydrogels, Anionic Polymerisation Nanocomposites. Springer, 2000: 37-65.
[9] Zhang H, Xia H, Zhao Y. Poly(vinyl alcohol) hydrogel can autonomously self-heal[J]. ACS Macro Letters, 2012, 1(11): 1233-1236.
[10] Butylina S, Geng S, Oksman K. Properties of as-prepared and freeze-dried hydrogels made from poly(vinyl alcohol) and cellulose nanocrystals using freeze-thaw technique[J]. European Polymer Journal, 2016, 81: 386-396.
[11] Liu Huaqing, Yang Jun. Synthesis and Research of Chemically Crosslinked Polyvinyl Alcohol (PVA) Hydrogels[J]. Shandong Chemical Industry, 2013, 42(7): 1-4.
[12] Peppas N A, Merrill E W. Differential scanning calorimetry of crystallized PVA hydrogels[J]. Journal of Applied Polymer Science, 1976, 20(6): 1457-1465.
[13] Sun J Y, Zhao X, Illeperuma W R K, et al. Highly stretchable and tough hydrogels[J]. Nature, 2012, 489(7414): 133-136.
[14] Gong J P, Katsuyama Y, Kurokawa T, et al. Double-network hydrogels with extremely high mechanical strength[J]. Advanced Materials, 2003, 15(14): 1155-1158.
[15] Chen Q, Zhu L, Zhao C, et al. A robust, one-pot synthesis of highly mechanical and recoverable double network hydrogels using thermoreversible sol-gel polysaccharide[J]. Advanced Materials, 2013, 25(30): 4171-4176.
[16] Deformation and Failure Behavior of High Toughness Hydrogels[J]. Journal of Functional Polymers, 2023, 36(3): 203-220.
[17] Ren C.L., Chen T., Bao B.K., et al. Research Progress on High-Strength and High-Toughness Gelatin Hydrogels. Polymer Bulletin, 2026, 39(01): 97-124.
[18] Liao Z.Y., Chen X.Y., Yao X.L., et al. Advances in the Formation and Self-Healing Mechanisms of Double Network Hydrogels. Modern Food Science and Technology, 2022, 38(1): 398-410.
[19] Ma S.S., Yue Y.N., Liu J., et al. Preparation and Properties of Dialdehyde Microfibrillated Cellulose/Polyvinyl Alcohol Composite Hydrogels with Tunable Mechanical Strength. Polymer Materials Science and Engineering, 2023, 39(5): 1-10.
[20] Zheng Q F, Zhao L Y, Wang J, et al. High-strength and high-toughness sodium alginate/polyacrylamide double physically crosslinked network hydrogel with superior self-healing and self-recovery properties prepared by a one-pot method[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 589: 124402.
[21] Wang Y., Lyu G.J., Xia M.Y., et al. Research Progress on Biomass-Based Hydrogel Functional Materials. China Pulp & Paper, 2023, 42(04): 123-131.
[22] Zainal S H, Mohd N H, Suhaili N, et al. Preparation of cellulose-based hydrogel: A review[J]. Journal of Materials Research and Technology, 2021, 10: 935-952.
[23] Cui Y.X., Quan Y.N., Liu W.D., et al. Construction and Application of Cellulose-Based Hydrogels. Journal of Materials Engineering, 2023, 51(9): 37-51.
[24] Gao G R, Du G L, Sun Y N, et al. Self-healable, tough, and ultrastretchable nanocomposite hydrogels based on reversible polyacrylamide/montmorillonite adsorption[J]. ACS Applied Materials & Interfaces, 2015, 7(8): 5029-5037.
[25] Zhang S.L., Gu Y., Zhang Y., et al. Research status of nano-micron particle enhancers for polyacrylamide gel systems used in oilfield chemistry. Applied Chemical Industry, 2023, 52(10): 1-8.
[26] Liu R, Liang S, Tang X Z, et al. Tough and highly stretchable graphene oxide/polyacrylamide nanocomposite hydrogels[J]. Journal of Materials Chemistry, 2012, 22(28): 14160-14167.
[27] Li Z, Yu C, Kumar H, et al. The effect of crosslinking degree of hydrogels on hydrogel adhesion[J]. Gels, 2022, 8(10): 682.
[28] Yan S.T. Research Progress on Marine Antifouling Hydrogels. Applied Chemical Industry, 2024, 53(1): 1-6.
[29] Wu S, Hua M, Alsaid Y, et al. Poly(vinyl alcohol) hydrogels with broad-range tunable mechanical properties via the Hofmeister effect[J]. Advanced Materials, 2021, 33(11): 2007829.
[30] Wang J.H., Yan M.L., Yu R.H., et al. Preparation and Properties of Iron Ion-Enhanced Sodium Alginate-Based Hydrogels. Journal of Nanchang Hangkong University (Natural Science Edition), 2025, 39(01): 91-99.
[31] Hou P., Li M., Ma J., et al. Preparation and Application Progress of Natural Polymer Material Hydrogels. Materials Reports, 2022, 36(8): 1-12.
[32] Liang Y.F., Tao D., Huang Y.N., et al. Research Progress of Polyvinyl Alcohol Hydrogel-Based Flexible Strain Sensors. Micronanoelectronic Technology, 2023, 60(12): 1907-1927.
[33] Zhang X.L., Li M.Q., Li X., et al. Research Progress of Sodium Alginate Hydrogels. Materials Science, 2023, 13(6): 579-588.
[34] Wu Z., Qu S.G., Feng L.T., et al. Adsorption Performance and Mechanism of Sodium Alginate/Microcrystalline Cellulose Composite Hydrogel for Methyl Orange and Methylene Blue in Water. Chemical Industry and Engineering Progress, 2023, 42(12): 1-14.
[35] Huang Y.X., Wang W., Yang T., et al. Research Progress of Chitosan-Based Hydrogels for Wound Dressings. Journal of Hangzhou Normal University (Natural Science Edition), 2023, 22(03): 233-239.
[36] Ladeira N M B, Donnici C L, de Mesquita J P, et al. Preparation and characterization of hydrogels obtained from chitosan and carboxymethyl chitosan[J]. Journal of Polymer Research, 2021, 28(9): 335.
[37] Yang J, Chen Y, Zhao L, et al. Constructions and properties of physically cross-linked hydrogels based on natural polymers[J]. Polymer Reviews, 2023, 63(3): 1-40.
[38] Thakur S, Govender P P, Mamo M A, et al. Recent progress in gelatin hydrogel nanocomposites for water purification and beyond[J]. Vacuum, 2017, 146: 396-408.
[39] Xue B, Bashir Z, Guo Y, et al. Strong, tough, rapid-recovery, and fatigue-resistant hydrogels made of picot peptide fibres[J]. Nature Communications, 2023, 14(1): 2583.
[40] Yan X.Y., Dan N.H., Chen Y.N., et al. Research Status and Characteristic Analysis of Polymer Hydrogels. Chemical World, 2023, 64(03): 129-140. DOI: 10.19500/j.cnki.0367-6358.20210604.
[41] Okumura Y, Ito K. The polyrotaxane gel: A topological gel by figure-of-eight cross-links[J]. Advanced Materials, 2001, 13(7): 485-487.
[42] Zhao X.Q., Liu X., Zhou Z.R., et al. Research Status of Strengthening and Toughening Strategies and Preparation Methods of Hydrogels with Microphase Separation Structure. Polymer Materials Science and Engineering, 2022, 38(12).
[43] Sakai T, Matsunaga T, Yamamoto Y, et al. Design and fabrication of a high-strength hydrogel with ideally homogeneous network structure from tetrahedron-like macromonomers[J]. Macromolecules, 2008, 41(14): 5379-5384.
[44] Lin X, Zhao X, Xu C, et al. Progress in the mechanical enhancement of hydrogels: Fabrication strategies and underlying mechanisms[J]. Journal of Polymer Science, 2022, 60(17): 2525-2542.
[45] Guo S.C., Xing R.Q., Du X.C., et al. Preparation and Properties of Polydioxanone/Polyvinyl Alcohol Composite Hydrogels. Polymer Materials Science and Engineering, 2023, 39(12): 1-11.
[46] Kang B, Lang Q, Tu J, et al. Preparation and properties of double network hydrogel with high compressive strength[J]. Polymers, 2022, 14(5): 966.
[47] Wu Y., Wang S.F., Li Y.L., et al. Preparation and Properties of Poly(N-isopropylacrylamide)/Poly(acrylic acid) Hydrogel. Shandong Chemical Industry, 2024, 53(1): 38-41.
[48] Li Liqing, Wu Panwang, Ma Jie. Construction of double-network gel sorbent and its application in water pollutant removal[J].Progress in Chemistry,2021,33(06):1010-1025.
[49] Brown H R. A model of the fracture of double network gels[J]. Macromolecules, 2007, 40(10): 3815-3818.
[50] Tanaka Y. A local damage model for anomalous high toughness of double-network gels[J]. Europhysics Letters, 2007, 78(5): 56005.
[51] Matsuda T, Kawakami R, Namba R, et al. Mechanoresponsive self-growing hydrogels inspired by muscle training[J]. Science, 2019, 363(6426): 504-508.
[52] Zheng D, Lin S, Ni J, et al. Fracture and fatigue of entangled and unentangled polymer networks[J]. Extreme Mechanics Letters, 2022, 51: 101608.
[53] Kim J, Zhang G, Shi M, et al. Fracture, fatigue, and friction of polymers in which entanglements greatly outnumber cross-links[J]. Science, 2021, 374(6564): 212-216.
[54] Zhang J.Y., Qu D.Z., Wang S.Y., et al. Research Progress and Application of Polymer-Based Hydrogels. China Adhesives, 2023, 32(8): 48-59.
[55] Long R, Hui C Y. Fracture toughness of hydrogels: Measurement and interpretation[J]. Soft Matter, 2016, 12(39): 8069-8086.
[56] Lake G L, Thomas A G. The strength of highly elastic materials[J]. Proceedings of the Royal Society of London A, 1967, 300(1460): 108-119.
[57] Zhang W, Hu J, Tang J, et al. Fracture toughness and fatigue threshold of tough hydrogels[J]. ACS Macro Letters, 2019, 8(1): 17-23.
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