The Application of Nuclear Magnetic Resonance Technology in Study of Concrete Materials

Authors

  • Linlin Bai
  • Xiaosheng Song

DOI:

https://doi.org/10.54691/wfxdyw81

Keywords:

Concrete, nuclear magnetic resonance, solid-state nuclear magnetic resonance, pore structure.

Abstract

As one of the most widely used structural materials in modern society, the optimization and improvement of concrete performance has always been a hot topic in material science research. As a non-destructive analysis method, nuclear magnetic resonance ( NMR ) technology has shown unique advantages in the study of concrete materials because it can provide material microstructure and dynamic information. This paper reviews the application of nuclear magnetic resonance technology in the hydration process, pore structure analysis and durability evaluation of concrete materials, and discusses the application progress of nuclear magnetic resonance technology in the quantitative analysis of cement-based materials. By analyzing the advantages and limitations of different nuclear magnetic resonance techniques, it provides theoretical basis and technical support for further research and engineering application of concrete materials.

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References

[1] J.H. Lee, B. Cho, E. Choi. Flexural capacity of fiber reinforced concrete with a consideration of concrete strength and fiber content. Construction and Building Materials, Vol. 138 (2017), p.222-231.

[2] Y.J. Chen, F. AL-Neshawy, J. Punkki. Investigation on the effect of entrained air on pore structure in hardened concrete using MIP. Construction and Building Materials, Vol. 292 (2021), 123441

[3] Z.D. Zhu, W.W. Huo, H. Sun, et al. Correlations between unconfined compressive strength, sorptivity and pore structures for geopolymer based on SEM and MIP measurements. Journal of Building Engineering, Vol. 67 (2023), 106011.

[4] S.W. Tang, Z. He, X.H. Cai, et al. Volume and surface fractal dimensions of pore structure by NAD and LTDSC in calcium sulfoaluminate cement pastes. Construction and Building Materials, Vol. 143 (2017), p. 395-418.

[5] J.J. VÖLkl, R.E. Beddoe, M.J. Setzer. The specific surface of hardened cement paste by small-angle X-ray scattering effect of moisture content and chlorides. Cement and Concrete Research, Vol. 17 (1987) No. 1, p. 81-88.

[6] A.C Forse, C. Merlet, C.P. Grey, et al. NMR studies of adsorption and diffusion in porous carbonaceous materials. Progress in Nuclear Magnetic Resonance Spectroscopy, Vol. 124 (2021) , p. 57-84.

[7] Q. Zeng, M.Y. Luo, X.Y. Pang, et al. Surface fractal dimension: An indicator to characterize the microstructure of cement-based porous materials. Applied Surface Science, Vol. 282 (2013), p. 302-307.

[8] H.J. Fu, X.Z. Wang, L.X. Zhang, et al. Investigation of the factors that control the development of pore structure in lacustrine shale: A case study of block X in the Ordos Basin, China. Journal of Natural Gas Science and Engineering, Vol. 26 (2015), p. 1422-1432.

[9] X.H. Ma, H.Y. Wang, S.W. Zhou, et al. Insights into NMR response characteristics of shales and its application in shale gas reservoir evaluation. Journal of Natural Gas Science and Engineering, Vol. 84 (2020), 103674

[10] S.Y. Zhang, S.Q. Zhang, E. Wang, et al. Grey model study on strength and pore structure of self-compacting concrete with different aggregates based on NMR. Journal of Building Engineering, Vol. 64 (2023), 105560.

[11] M. Fleury, T. Chevalier, G. Berthe, et al. Water diffusion measurements in cement paste, mortar and concrete using a fast NMR based technique. Construction and Building Materials, Vol. 259 (2020), 119843.

[12] R. Kurihara, I. Maruyama. Surface area development of Portland cement paste during hydration: Direct comparison with 1H NMR relaxometry and water vapor/nitrogen sorption. Cement and Concrete Research,. Vol. 157 (2022), 106805.

[13] C. Glawe, F. Georget, M. Raupach, et al. Multi technique characterization of the carbonation affected zone including non-destructive single sided 1H NMR. Cement and Concrete Research, Vol. 178 (2024), 107438.

[14] R.S. Holthausen, M. Raupach. Monitoring the internal swelling in cementitious mortars with single-sided 1H nuclear magnetic resonance. Cement and Concrete Research, Vol. 111 (2018), p. 138-146.

[15] Y.H. Fang: Principles of High Resolution Solid-state Nuclear Magnetic Resonance and Its Application in Research of Cement Chemistry. Journal of Building Materials, Vol. 01 (2003), p. 54-60. (In Chinese)

[16] X.G. Xi, Z.Z. Xu. Application of solid-state nuclear magnetic resonance in the study of cement concrete materials. Jiangsu Building Materials, Vol. 01 (2003) No. 9, p. 19-20. (In Chinese)

[17] H.E. Gottlieb, V. Kotlyar, A. Nudelman. NMR Chemical Shift sof Common Laboratory Solven tsas Trace Impurities . J. Org. Chem. Vol. 62 (1997) No. 21, p. 7512-7515.

[18] L. Wang, Z. He, H.Q Yang, et al. Study on the microstructural mechanism to improve the abrasion resistance of concrete by adding silica fume. Journal of Hydraulic Engineering, Vol. 01 (2003), p. 111-118. (In Chinese)

[19] X. Wang: Drying Shrinkage of Hardened Cement Paste and Its Relationship to the Microstructure(MS., Chongqing University, China 2011).

[20] F. Méducin, B. Bresson, N. Lequeux, et al. Calcium silicate hydrates investigated by solid-state high resolution 1H and 29Si nuclear magnetic resonance. Cement and Concrete Research, Vol. 37 (2007) No. 05, p. 631-638.

[21] J. Rottstegge, M. Wilhelm, H.W. Spiess. Solid State Nmr Investigations on the Role of Organic Admixtures on the Hydration of Cement Pastes. Cement & Concrete Composites, Vol. 28 (2006) No. 5, p. 417-426.

[22] G.S. Huang, L. Su, C.Z. Xue, et al. Analysis on pore characteristics of hybrid basalt-polypropylene fiber-reinforced concrete based on nuclear magnetic resonance technology. Acta Materiae Compositae Sinica. (In Chinese)

[23] D. Gastaldi, G. Paul, L. Marchese, et al. Hydration products in sulfoaluminate cements: Evaluation of amorphous phases by XRD/solid-state NMR. Cement and Concrete Research, Vol. 90 (2016), p. 162-173.

[24] P. Bhardwaj, R. Gupta, D. Mishra, et al. Quadrifunctionality Variation of Aluminosilicate Silicon Nucleus on Solid State Geopolymerisation Observed by 29Si Magic Angle Spinning Nuclear Magnetic Resonance Studies. Silicon, Vol. 11 (2019) No. 4, p. 2127-2133.

[25] M. Fardis, G. Papavassiliou, L. Abulnasr, et al. Effect of Clay-Minerals on the Hydration of Cement-an Nmr-Study. Advanced Cement Based Materials, Vol. 1 (1994) No. 16, p. 243-247.

[26] A. She, W. Yao, Y. Wei. In-situ Monitoring of Hydration Kinetics of Cement Pastes by Low-field NMR. Journal Of Wuhan University Of Technology-Materials Science Edition, Vol. 25 (2010) No. 4, p. 692-695.

[27] P. Faure, U. Peter, D. Lesueur, et al.. Water transfers within Hemp Lime Concrete followed by NMR. Cement and Concrete Research, Vol. 42 (2012) No. 11, p. 1468-1474.

[28] M. Pang, Z. Sun, Q. Li, et al. 1H NMR Spin-Lattice Relaxometry of Cement Pastes with Polycarboxylate Superplasticizers. Materials, Vol. 13 (2020) No. 24, p. 692-695.

[29] C. Casieri, F. De Luca, L. Nodari, et al. Detection of Magnetic Environments in Porous Media by Low-Field 2d NMR Relaxometry. Chemical Physics Letters, Vol. 496 (2010) No. 1-3, p. 223-226.

[30] L. Tan, C.F. Wie, H.H. Tian, et al. Experimental Study of Unfrozen Water Content of Frozen Soils by Low-field Nuclear Magnetic Resonance. Rock and Soil Mechanics, Vol. 36 (2015) No. 06, p. 1566-1572. (In Chinese)

[31] Y.D. He, Z.Q. Mao, L.Z. Xiao, et al. A New Method to Obtain Capillary Pressure Curve Using NMR T_2 Distribution. Journal of Jiling University (Earth Science Edition), Vol. 02 (2005) p. 177-181. (In Chinese)

[32] X.W. Wang, Z.M. LI, H.B. Yang, et al. Experimental Study on Pore Structure of Low Permeability Core with NMR Spectra. Journal of Southwest Petroleum University(Science & Technology Edition), Vol. 32 (2010) No. 02, p. 69-72+199. (In Chinese)

[33] S.T. Bai, D.J. Cheng, J.B. Wan, et al. Q Uantitative Characterization of Sandstone NMR T_2 Spectrum, Acta Petrolei Sinica, Vol. 37 (2016) No. 03, p. 382-391+414. (In Chinese)

[34] X.X. Wang, X.D. Shen, H.L. Wang, et al. Nuclear Magnetic Resonance Analysis of Freeze-Thaw Damage in Natural Pumice Concrete. MATERIALES DE CONSTRUCCION, Vol. 66 (2016) No. 322, p. 382-391+414.

[35] X.H. Deng, X.Y. Gao, R. Wang, et al. (2021). Investigation of Microstructural Damage in Air-Entrained Recycled Concrete under a Freeze-Thaw Environment. CONSTRUCTION AND BUILDING MATERIALS, Vol. 268 (2021).

[36] S.Y. Zhang, S.Q. Zheng, E. Wang, et al. Grey Model Study on Strength and Pore Structure of Self-Compacting Concrete with Different Aggregates Based on NMR. JOURNAL OF BUILDING ENGINEERING,

[37] H. Wu, W.P Xue, Z.J. Wang. Pore Structure Fractal Characteristics of PVA Fiber Concrete under Salt Erosion and Freeze-Thaw Cycle. Bulletin of the Chinese Ceramic Society. Vol. 43 (2024) No. 05, p. 1859-1866. (In Chinese)

[38] K.D. Wang, W.J. Wang, Y.D. Guo, et al. Grey Modeling Study on Mechanical Properties and Pore Structure of Concrete with Different Basalt Fiber Contents Based on NMR. JOURNAL OF BUILDING ENGINEERING, Vol. 89 (2024).

[39] Z.C. Wang, K. Wu, S.Y. Liu, et al. Exploring Pore Structure Characteristics of Alkali Residue-Based Foamed Concrete and Their Effect on Compressive Properties: Insights from Low-Field Nuclear Magnetic Resonance Analysis. Journal of Materials in Civil Engineering, Vol. 36(2024).

[40] S.G. Dong, G.J. Zhang, L.Y. Hou, et al. Analysis of the Relationship Between the Porosity and the Salt Freezing Resistance of Concrete by NMR Data. Journal of Chinese Electron Microscopy Society, Vol. 34 (2015) No. 05, p. 428-432. (In Chinese)

[41] L. Shi, J. Wang, Z.X. Zhang. Research on Microstructure Water Evolution Law of Standard Curing Process of Concrete Based on Low-Field Nuclear Magnetic Technology. Hans Journal of Civil Engineering, Vol. 13 (2024) No. 5, p. 744-752. (In Chinese)

[42] X.H. Wang, N.D. Jike, S. Chen, et al. Water Imbibition in Concrete In-Situ Traced by Transmission X-ray Radiography. Journal of Zhejiang University(Engineering Science), Vol. 55 (2021) No. 04, p. 727-732+792. (In Chinese)

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Published

20-05-2026

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